Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation

This manuscript reports a visible-light-mediated organosulfide catalysis that enables the decarboxylative coupling between simple aliphatic alcohol and tertiary or secondary alkyl carboxylic acid-derived redox active esters to produce a C­(sp3)–O–C­(sp3) fragment. Results of the coupling using other...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2020-01, Vol.142 (3), p.1211-1216
Main Authors: Shibutani, Shotaro, Kodo, Taiga, Takeda, Mitsutaka, Nagao, Kazunori, Tokunaga, Norihito, Sasaki, Yusuke, Ohmiya, Hirohisa
Format: Article
Language:English
Subjects:
alcohols
amides
catalytic activity
esters
Lewis bases
reaction mechanisms
thiols
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