Pyrolytic remediation of crude oil-contaminated soil

• Published in: The Science of the total environment 2020-04, Vol.713, p.136498-136498, Article 136498
• Main Authors: Kang, Chan-Ung, Kim, Do-Hyeon, Khan, Moonis Ali, Kumar, Rahul, Ji, Seung-Eun, Choi, Kung-Won, Paeng, Ki-Jung, Park, Sungmin, Jeon, Byong-Hun
• Format: Article
• Language: English
• Subjects: Crude oil; Pyrolysis; Remediation; Soil
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2020.136498

Deterioration of our terrestrial environment due to decreasing soil quality brought on by crude oil spills and leakages is a major issue. In this study, soil samples were prepared by mixing clay (bentonite) and sand contaminated with 5 and 10 wt% crude oil (in order to study the effect of oil concentration), and weathered in a laboratory to simulate actual contaminated soil. Volatilization of light oil was inhibited in clay rich-soil, resulting in higher contamination after weathering. The efficiency of the pyrolytic treatment was evaluated by comparing the weight change and n-hexane extractable material (HEM) content of the soil samples. The working temperature influenced pyrolysis efficiency more than the reaction time. A residual amount of 0.29–0.61 wt% (below the soil pollution standard) was observed in the samples with high clay content and pollution level (by pyrolysis for 30 min at 400 °C). Infrared analysis of treated soil samples showed a reduction in alkyl functionality (CH), confirming a decrease in hydrophobicity and an improvement in water holding capacity (WHC). Seed germination and plant growth were relatively better in the pyrolyzed soil. The field applicability of the pyrolytic treatment process was confirmed at laboratory and pilot scale, as well as by treating soil samples collected from actual polluted sites. [Display omitted] •Pyrolysis was used to remediate crude oil-contaminated soil.•Pyrolysis temperature influenced remediation efficiency more than the residence time.•FTIR and GC × GC confirmed changes in hydrocarbon composition.•Pyrolysis successfully treated real polluted soils in continuous treatment mode.•Seed germination was increased >50% in remediated soils.