Accurate Prediction of the S1 Excitation Energy in Solvated Azobenzene Derivatives via Embedded Orbital-Tuned Bethe-Salpeter Calculations

By employing the Bethe-Salpeter formalism coupled with a nonequilibrium embedding scheme, we demonstrate that the paradigmatic case of S1 band separation between cis and trans in azobenzene derivatives can be computed with excellent accuracy compared to experimental optical spectra. Besides embeddin...

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Bibliographic Details
Published in:Journal of chemical theory and computation 2020-04, Vol.16 (4), p.2021-2027
Main Authors: Kshirsagar, Aseem Rajan, D’Avino, Gabriele, Blase, Xavier, Li, Jing, Poloni, Roberta
Format: Article
Language:English
Subjects:
Derivatives
Embedding
Excitation
Ionization potentials
Iterative methods
Online Access:Get full text
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Summary:By employing the Bethe-Salpeter formalism coupled with a nonequilibrium embedding scheme, we demonstrate that the paradigmatic case of S1 band separation between cis and trans in azobenzene derivatives can be computed with excellent accuracy compared to experimental optical spectra. Besides embedding, we show that the choice of the Kohn–Sham exchange correlation functional for DFT is critical, despite the iterative convergence of GW quasiparticle energies. We address this by adopting an orbital-tuning approach via the global hybrid functional, PBEh, yielding an environment-consistent ionization potential. The vertical excitation energy of 20 azo molecules is predicted with a mean absolute error as low as 0.06 eV, up to three times smaller compared to standard functionals such as M06-2X and PBE0, and five times smaller compared to recent TDDFT results.
ISSN:1549-9618
1549-9626
DOI:10.1021/acs.jctc.9b01257