Time-Resolved Temperature-Jump Infrared Spectroscopy at a High Repetition Rate

Time-resolved temperature-jump infrared absorption spectroscopy at a 0.5 to 1 kHz repetition rate is presented. A 1 kHz neodymium-doped yttrium aluminum garnet (Nd:YAG) laser pumping an optical parametric oscillator provided >70 µJ, 3.75 µm pump pulses, which delivered a temperature jump via exci...

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Bibliographic Details
Published in:Applied spectroscopy 2020-06, Vol.74 (6), p.720-727
Main Authors: Greetham, Gregory M., Clark, Ian P., Young, Benjamin, Fritsch, Robby, Minnes, Lucy, Hunt, Neil T., Towrie, Mike
Format: Article
Language:English
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Summary:Time-resolved temperature-jump infrared absorption spectroscopy at a 0.5 to 1 kHz repetition rate is presented. A 1 kHz neodymium-doped yttrium aluminum garnet (Nd:YAG) laser pumping an optical parametric oscillator provided >70 µJ, 3.75 µm pump pulses, which delivered a temperature jump via excitation of the O–D stretch of a D2O solution. A 10 kHz train of mid-infrared probe pulses was used to monitor spectral changes following the temperature jump. Calibration with trifluoroacetic acid solution showed that a temperature jump of 10 K lasting for tens of microseconds was achieved, sufficient to observe fast processes in functionally relevant biomolecular mechanisms. Modeling of heating profiles across ≤10 µm path length cells and subsequent cooling dynamics are used to describe the initial 10 µs cooling dynamics of the bulk solution.
ISSN:0003-7028
1943-3530
DOI:10.1177/0003702820913636