Photoisomerization dynamics of trans–trans, cis–trans, and cis–cis diphenylbutadiene from broadband transient absorption spectroscopy and calculations

The photoisomerization path and dynamics of trans–trans (ttD), cis–trans (ctD), and cis–cis (ccD) 1,4-diphenyl-1,3-butadiene (DPB) in solution are studied with broadband transient absorption (TA) spectroscopy and quantum chemical calculations. For ttD in n-hexane, 2-photon-excited TA spectra indicat...

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Bibliographic Details
Published in:The Journal of chemical physics 2020-06, Vol.152 (22), p.224305
Main Authors: Krohn, O. A., Quick, M., Sudarkova, S. M., Ioffe, I. N., Richter, C., Kovalenko, S. A.
Format: Article
Language:English
Subjects:
Absorption spectra
Acetonitrile
Broadband
Butadiene
Chemical bonds
Dipole moments
Excitation spectra
Isomerization
Mathematical analysis
Photons
Physics
Polarity
Quantum chemistry
Spectrum analysis
Stilbene
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