Triple-bridged helical binuclear copper() complexes: Head-to-head and head-to-tail isomerism and the solid-state luminescence

A family of helical dinuclear copper( i ) pyridylphospholane complexes [Cu 2 L 3 X]X (X = BF 4 − , Cl − and Br − ) was prepared. The family includes the first examples of this type of complex based on copper( i ) chloride and copper( i ) bromide. The two isomers typical of this class of compounds, n...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2020-09, Vol.49 (34), p.11997-128
Main Authors: Shamsieva, Aliia V, Musina, Elvira I, Gerasimova, Tatiana P, Strelnik, Igor D, Strelnik, Anna G, Kolesnikov, Ilya E, Kalinichev, Alexey A, Islamov, Daut R, Samigullina, Aida I, Lönnecke, Peter, Katsyuba, Sergey A, Hey-Hawkins, Evamarie, Karasik, Andrey A, Sinyashin, Oleg G
Format: Article
Language:English
Subjects:
Chemical bonds
Chlorides
Coordination compounds
Copper
Copper compounds
Crystallography
Hydrogen bonding
Isomers
Luminescence
Mathematical analysis
NMR
Nuclear magnetic resonance
Optics
Quantum chemistry
Single crystals
Solid state
Water chemistry
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