Room‐Temperature Bistability in a Ni–Fe Chain: Electron Transfer Controlled by Temperature, Pressure, Light, and Humidity

Bistable and stimuli‐responsive molecule‐based materials are promising candidates for the development of molecular switches and sensors for future technologies. The CN‐bridged NH4[Ni(cyclam)][Fe(CN)6]⋅5 H2On chain exists in two valence states: NiII‐FeIII (1HT) and NiIII‐FeII (1LT) and shows unique m...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2021-02, Vol.60 (5), p.2330-2338
Main Authors: Reczyński, Mateusz, Pinkowicz, Dawid, Nakabayashi, Koji, Näther, Christian, Stanek, Jan, Kozieł, Marcin, Kalinowska‐Tłuścik, Justyna, Sieklucka, Barbara, Ohkoshi, Shin‐ichi, Nowicka, Beata
Format: Article
Language:English
Subjects:
Bistability
Chains
Dehydration
Electron transfer
High temperature
Humidity
Iron
Irradiation
Magnetic permeability
Magnetic susceptibility
Molecular machines
molecular switches
multiresponsivity
Nickel
Phase transitions
Pressure
Radiation
Stimuli
Switches
Temperature
Valence
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