Co(III), Rh(III) & Ir(III)‐Catalyzed Direct C−H Alkylation/Alkenylation/Arylation with Carbene Precursors

Metal carbenes play a pivotal role in transition‐metal‐catalyzed synthetic transfer reactions. The metal carbene is generated either from a diazo compound through facile extrusion of N2 with a metal catalyst or in situ generated from other sources like triazoles, pyriodotriazoles, sulfoxonium ylides...

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Bibliographic Details
Published in:Chemistry, an Asian journal an Asian journal, 2021-03, Vol.16 (5), p.443-459
Main Authors: Nunewar, Saiprasad, Kumar, Sanjeev, Talakola, Srilakshmi, Nanduri, Srinivas, Kanchupalli, Vinaykumar
Format: Article
Language:English
Subjects:
Alkylation
Antifungal agents
carbene precursors
Carbenes
Chemical reactions
Chemistry
C−H activation
Extrusion
Insertion
migratory insertions
Precursors
Rh(III) and Ir(III) catalysts
Rhodium
Triazoles
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