Mild and Selective Rhodium-Catalyzed Transfer Hydrogenation of Functionalized Arenes

Diboron-mediated rhodium-catalyzed transfer hydrogenation of functionalized arenes is reported. In addition to good functional group tolerance, the reaction features operational simplicity and controllable chemoselectivity. The general applicability of this procedure is demonstrated by the selective...

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Published in:Organic letters 2021-03, Vol.23 (5), p.1910-1914
Main Authors: Wang, Yuhan, Chang, Zhiqian, Hu, Yan, Lin, Xiao, Dou, Xiaowei
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Language:English
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cited_by cdi_FETCH-LOGICAL-a345t-dc1c8b6f5699633c33edb3fd9097232cee3a005ab96adf5ea177d9cd8c8c06f73
cites cdi_FETCH-LOGICAL-a345t-dc1c8b6f5699633c33edb3fd9097232cee3a005ab96adf5ea177d9cd8c8c06f73
container_end_page 1914
container_issue 5
container_start_page 1910
container_title Organic letters
container_volume 23
creator Wang, Yuhan
Chang, Zhiqian
Hu, Yan
Lin, Xiao
Dou, Xiaowei
description Diboron-mediated rhodium-catalyzed transfer hydrogenation of functionalized arenes is reported. In addition to good functional group tolerance, the reaction features operational simplicity and controllable chemoselectivity. The general applicability of this procedure is demonstrated by the selective hydrogenation of a range of arenes, including functionalized benzenes, biphenyls, and polyaromatics.
doi_str_mv 10.1021/acs.orglett.1c00341
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title Mild and Selective Rhodium-Catalyzed Transfer Hydrogenation of Functionalized Arenes
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