Concise enantioselective synthesis of wine lactone via intramolecular Diels–Alder reaction

ABSTRACT An enantioselective synthesis of (3S,3aS,7aR)-wine lactone, a major aroma component of white wine and citrus juices, was achieved starting from (S)-2-methyl-3-butenoic acid. An intramolecular Diels–Alder reaction was employed as a key step. Graphical Abstract Graphical Abstract An enantiose...

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Bibliographic Details
Published in:Bioscience, biotechnology, and biochemistry biotechnology, and biochemistry, 2021-05, Vol.85 (6), p.1390-1394
Main Authors: Ohkubo, Yasutaka, Masuda, Yui, Ogura, Yusuke, Takikawa, Hirosato, Watanabe, Hidenori
Format: Article
Language:English
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Summary:ABSTRACT An enantioselective synthesis of (3S,3aS,7aR)-wine lactone, a major aroma component of white wine and citrus juices, was achieved starting from (S)-2-methyl-3-butenoic acid. An intramolecular Diels–Alder reaction was employed as a key step. Graphical Abstract Graphical Abstract An enantioselective synthesis of (3S,3aS,7aR)-wine lactone was achieved.
ISSN:1347-6947
1347-6947
DOI:10.1093/bbb/zbab045