Regioselective C(sp)-H alkylation of a fructopyranose derivative by 1,6-HAT

Regioselective C(sp 3 )-H alkylation of a fructopyranose derivative using electron-deficient alkenes as alkylation reagents was achieved. The reaction proceeded via 1,6-hydrogen atom transfer under photoredox iridium catalysis. Several functional groups were introduced into the fructopyranose deriva...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2021-04, Vol.19 (14), p.3124-3127
Main Authors: Li, Yanru, Miyamoto, Shoto, Torigoe, Takeru, Kuninobu, Yoichiro
Format: Article
Language:English
Subjects:
Alkenes
Alkylation
Catalysis
Functional groups
Iridium
NMR
Nuclear magnetic resonance
Reagents
Regioselectivity
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