Synthesizing Photoluminescent Au28(SCH2Ph‐tBu)22 Nanoclusters with Structural Features by Using a Combined Method

We present a method for atomically precise nanocluster synthesis. As an illustration, we introduced the reducing‐ligand induction combined method and synthesized a novel nanocluster, which was determined to be Au28(SCH2Ph‐tBu)22 with the same number of gold atoms as existing Au28(SR)20 nanoclusters...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2021-08, Vol.60 (33), p.17932-17936
Main Authors: Dong, Jingwu, Gan, Zibao, Gu, Wanmiao, You, Qing, Zhao, Yan, Zha, Jun, Li, Jin, Deng, Haiteng, Yan, Nan, Wu, Zhikun
Format: Article
Language:English
Subjects:
Atomic properties
Au28(SCH2Ph-tBu)22
Charge transfer
Gold
hetero-composition-homo-size
Hydrophobicity
Kernels
Ligands
metal nanoclusters
Nanoclusters
Photoluminescence
Photons
quasi-linear growth
structural photoluminescence
Synthesis
Tetrahedra
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