SuFEx Activation with Ca(NTf 2 ) 2 : A Unified Strategy to Access Sulfamides, Sulfamates, and Sulfonamides from S(VI) Fluorides

A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium triflimide and DABCO for SuFEx with amines is described. The reaction was applied to a diverse set of sulfamides, sulfamates, and sulfonamides at room temperature under mild conditions. Additionally, we hig...

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Bibliographic Details
Published in:Organic letters 2020-06, Vol.22 (11), p.4389-4394
Main Authors: Mahapatra, Subham, Woroch, Cristian P, Butler, Todd W, Carneiro, Sabrina N, Kwan, Sabrina C, Khasnavis, Samuel R, Gu, Junha, Dutra, Jason K, Vetelino, Beth C, Bellenger, Justin, Am Ende, Christopher W, Ball, Nicholas D
Format: Article
Language:English
Subjects:
ambient temperature
calcium
Letter
sulfamates
Online Access:Get full text
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