Effect of thermal treatments on chiral nematic cellulose nanocrystal films

• Published in: Carbohydrate polymers 2021-11, Vol.272, p.118404-118404, Article 118404
• Main Authors: Guidetti, Giulia, Frka-Petesic, Bruno, Dumanli, Ahu G., Hamad, Wadood Y., Vignolini, Silvia
• Format: Article
• Language: English
• Subjects: Carbon - chemistry; Carbonisation; Cellulose - chemistry; Cellulose nanocrystals; Chiral carbon; Color; Cross-linking; Cross-Linking Reagents - chemistry; Electrochemistry - methods; Glutaral - chemistry; Hot Temperature; Microscopy, Electron, Scanning - methods; Nanoparticles - chemistry; Optical Phenomena; Photonic pigments; Spectroscopy, Fourier Transform Infrared - methods; Thermal stability; Thermogravimetry - methods
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2021.118404

The ability to manipulate the optical appearance of materials is essential in virtually all products and areas of technology. Structurally coloured chiral nematic cellulose nanocrystal (CNC) films proved to be an excellent platform to design optical appearance, as their response can be moulded by organising them in hierarchical architectures. Here, we study how thermal treatments influence the optical appearance of structurally coloured CNC films. We demonstrate that the CNCs helicoidal architecture and the chiral optical response can be maintained up to 250 °C after base treatment and cross-linking with glutaraldehyde, while, alternatively, an exposure to vacuum allows for the helicoidal arrangement to be further preserved up to 900 °C, thus producing aromatic chiral carbon. The ability to retain the helicoidal arrangement, and thus the visual appearance, in CNC films up to 250 °C is highly desirable for high temperature colour-based industrial applications and for passive colorimetric heat sensors. Similarly, the production of chiral carbon provides a new type of conductive carbon for electrochemical applications. •Glutaraldehyde crosslinking improves the optical contrast of helicoidal cellulose films.•Heat-treated cellulose nanocrystal films retain optical selectivity.•Carbonised cellulose nanocrystal films retain helicoidal assembly.