Fabrication of a Hydrophilic Low-Friction Poly(hydroxyethyl methacrylate) Coating on Silicon Rubber

• Published in: Langmuir 2021-11, Vol.37 (45), p.13493-13500
• Main Authors: Zhou, Shuaishuai, Qian, Shanhua, Wang, Wei, Ni, Zifeng, Yu, Jinghu
• Format: Article
• Language: English
• Subjects: Friction; Methacrylates; Polyhydroxyethyl Methacrylate; Rubber; Silicon; Surface Properties
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/acs.langmuir.1c02254

Silicon rubber has been widely used in the biomedical field due to its excellent mechanical properties and physiological inertia. However, the hydrophobic properties of silicon rubber surfaces limit their further application. Therefore, constructing a silicon rubber coating with hydrophilic and low-friction surface properties would be highly significant. Existing methods to achieve such coatings, including grafting polymer brushes and the deposition of hydrophilic materials, suffer from several deficiencies such as complicated coating processes and insufficient coating firmness. In this paper, we report a hydrophilic polymer poly­(hydroxyethyl methacrylate) (PHEMA) coating that can easily coat the surface of silicon rubber to provide low-friction performance. Sample silicon rubber was treated with benzophenone and hydroxyethyl methacrylate monomer solution in turn. The as-prepared coating was characterized by infrared spectroscopy, X-ray photoelectron spectroscopy, white light interference, and MFT-5000 wear test. The results indicated that the PHEMA coating had excellent hydrophilic properties (with a low contact angle of 9.39°) compared to uncoated silicon rubber. As the concentration of glycerol in the monomer solution was increased, the thickness and surface roughness of the as-prepared coating gradually decreased. The coating was firmly adsorbed on the substrate, and it had a zero-class bonding strength. In addition, the as-prepared coating demonstrated good friction-reduced properties, with the coefficient of friction being reduced by 98.0% compared with the uncoated silicon rubber in simulated blood. In summary, a hydrophilic and low-friction coating was successfully prepared using a simple method, and the results reported herein provide valuable insight into the surface design of similar soft materials.