Tailoring the Salt Transport Flux of Solar Evaporators for a Highly Effective Salt-Resistant Desalination with High Productivity

• Published in: ACS nano 2022-02, Vol.16 (2), p.2511-2520
• Main Authors: Yang, He, Sun, Yinghui, Peng, Meiwen, Cai, Mujin, Zhao, Bo, Li, Dan, Liang, Zhiqiang, Jiang, Lin
• Format: Article
• Language: English
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.1c09124

Developing highly effective salt-resistant solar evaporators for a long-term desalination with a high evaporation rate and water production rate remains a great challenge. Herein, we fabricated a three-dimensional printed hierarchical porous reduced graphene oxide/carbon black (3DP-HP rGO/CB) solar evaporator constructed with a thin layer of porous photothermal interface and a grid of hierarchical porous transport channel possessing a large-sized porous microstructure. The 3DP-HP rGO/CB solar evaporator demonstrates a tailored high-salt transport flux of up to 4.3 kg·m–2·h–1, which displays a highly effective salt-resistant performance at a high evaporation rate of 10.5 kg·m–2·h–1 during a desalination of 10 wt % NaCl brine under 8 kW·m–2 illumination. Experiments and theoretical calculations prove that the large porous microstructure with abundant and low-resistance salt ion channels endows solar evaporators with a high salt transport flux, therefore boosting salt resistance compared to traditional solar evaporators. A 10 d desalination experiment shows the long-term salt resistance of a 3DP-HP rGO/CB solar evaporator for a high-rate and stable evaporation and water production. Furthermore, the 3DP-HP rGO/CB evaporator can purify 10 wt % NaCl brine at an ultrafast water production rate of up to 5.6 L·m–2·h–1 under natural sunlight. This work demonstrates great potential for the practical implementation of solar desalination with high productivity.