Polydopamine/defective ultrathin mesoporous graphitic carbon nitride nanosheets as Z-scheme organic assembly for robust photothermal-photocatalytic performance

• Published in: Journal of colloid and interface science 2022-05, Vol.613, p.775-785
• Main Authors: Yang, Fan, Wang, Shijie, Li, Zhenzi, Xu, Yachao, Yang, Wutao, Yv, Chuanxin, Yang, Decai, Xie, Ying, Zhou, Wei
• Format: Article
• Language: English
• Subjects: Defect; Graphitic carbon nitride; Mesoporous structure; Photocatalysis; Photothermal effect; Z-scheme
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2022.01.012

Polydopamine/defective ultrathin mesoporous graphitic carbon nitride Z-scheme organic assembly is fabricated via N-vacancy defects and π-π interactions, which exhibits robust photocatalytic H2 production and contaminant degradation, due to the direct Z-scheme charge transfer mechanism to realize efficient spatial charge separation, and the enhanced photothermal effect to promote the photocatalytic reaction. [Display omitted] •Polydopamine/defective ultrathin mesoporous graphitic carbon nitride organic assemblies are fabricated.•N-vacancy and π-π interactions provide strong connection and fast charge transfer.•Z-scheme structure enables efficient of photogenerated charges separation.•Polydopamine extends photoabsorption and produces photothermal effect to improve catalyze activity. Polydopamine/defective ultrathin mesoporous graphitic carbon nitride (PDA/DCN) Z-scheme organic assembly is fabricated through high-temperature surface hydrogenation and ultrasonic freeze-dried strategies. PDA could be anchored on the surface of DCN with adequate N-vacancy defects firmly via π-π interactions, forming Z-scheme heterogenous structure for promoting charge separation. The visible and near-infrared light driven photocatalytic hydrogen evolution rate is up to 3420 μmol h−1 g−1, and the removal ratio of organic contaminant methylene blue is up to 98% within 70 min, which is several times higher than that of pristine graphitic carbon nitride and DCN. The important reason is the defects of DCN not only enhance the interaction with PDA, but also make the obvious polarized inbuilt electric field, and lead to Z-scheme structure for effective charge separation and rapid transfer, which is also confirmed by density functional theory (DFT) calculations. In addition, PDA extends the photoresponse to the near-infrared region and induces obvious photothermal effect to increase the reaction rate of the photocatalytic system. The efficient photothermal conversion of PDA/DCN should be another reason for the enhanced photocatalytic performance.