The hangman effect boosts hydrogen production by a manganese terpyridine complex

The manganese terpyridine complex 1 with a coordinated carboxylate in the axial position was obtained in situ . By virtue of a hangman effect, complex 1 catalyzes electrochemical hydrogen evolution from phenol in acetonitrile solution with a turnover frequency of 525 s −1 at a low overpotential of c...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (33), p.5128-5131
Main Authors: Wu, Qianqian, Li, Minghong, He, Shuanglin, Xiong, Ying, Zhang, Ping, Huang, Heyan, Chen, Lin, Huang, Fang, Li, Fei
Format: Article
Language:English
Subjects:
Acetonitrile
Carboxylic Acids
Hydrogen
Hydrogen evolution
Hydrogen production
Manganese
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Summary:The manganese terpyridine complex 1 with a coordinated carboxylate in the axial position was obtained in situ . By virtue of a hangman effect, complex 1 catalyzes electrochemical hydrogen evolution from phenol in acetonitrile solution with a turnover frequency of 525 s −1 at a low overpotential of ca. 230 mV. By virtue of a hangman effect, a manganese terpyridine complex catalyzes electrochemical hydrogen evolution from phenol in acetonitrile solution and achieves a turnover frequency of 525 s −1 with an overpotential of ca. 230 mV.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00757f