Synthesis of Enamines, Aldehydes, and Nitriles from CO2: Scope of the One-Pot Strategy via Formamides

Tetrabutylammonium acetate (TBAA) and Cu­(OAc)2 worked as a binary catalytic system for the solvent-free N-formylation of amines with CO2 and PhSiH3. This catalysis making C–H and C–N bonds with CO2 was coupled with the C–C bond-forming reactions to achieve the one-pot synthesis of enamines, aldehyd...

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Published in:Journal of organic chemistry 2023-11, Vol.88 (21), p.15444-15451
Main Authors: Nakaoka, Koichi, Guo, Chao, Saiki, Yuta, Furukawa, Shin, Ema, Tadashi
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container_issue 21
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container_title Journal of organic chemistry
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creator Nakaoka, Koichi
Guo, Chao
Saiki, Yuta
Furukawa, Shin
Ema, Tadashi
description Tetrabutylammonium acetate (TBAA) and Cu­(OAc)2 worked as a binary catalytic system for the solvent-free N-formylation of amines with CO2 and PhSiH3. This catalysis making C–H and C–N bonds with CO2 was coupled with the C–C bond-forming reactions to achieve the one-pot synthesis of enamines, aldehydes, and nitriles. The X-ray crystal structure of a Cu­(OAc)2–TBAA complex was also revealed.
doi_str_mv 10.1021/acs.joc.2c01666
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title Synthesis of Enamines, Aldehydes, and Nitriles from CO2: Scope of the One-Pot Strategy via Formamides
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