Low temperature sintering of a pottery clay from Burkina Faso

• Published in: Applied clay science 2000-11, Vol.17 (5), p.279-292
• Main Authors: Traoré, Karfa, Siméon Kabré, Tibo, Blanchart, Philippe
• Format: Article
• Language: English
• Subjects: Burkina Faso; calcium aluminosilicate; Earth sciences; Earth, ocean, space; Exact sciences and technology; kaolinite; Mineralogy; pottery; Silicates; sintering
• ISSN: 0169-1317; 1872-9053
• DOI: 10.1016/S0169-1317(00)00020-X

The sintering at 1000°C of a clay raw material for pottery mixed with calcite was studied to increase the mechanical characteristics of the fired product. The kaolinitic clay used comes from a large pottery production area in Burkina Faso. The experiments of this study were conducted as similar as possible to the traditional practices of potters to ensure a future technological transfer of results. An increase of the flexural strength from 7 to 17 mPa was obtained by adding 15% of calcite. To explain the mechanisms involved, the sintering behaviour was initially observed by dilatometry. Results indicated that at 1000°C, the maximum material densification and properties were obtained after about 15 min of dwell time. Therefore, a quantitative study of crystalline phases nucleated during this period was realised by X-ray diffraction methods. It revealed that anorthite is the most important phase formed during the firing time. Therefore, the nucleation mechanism, mostly involving quartz, but also gehlenite consumption was discussed. At the low firing temperature, it appears that the firing process is characterised by the absence of a liquid phase, drastically limiting the diffusion effect. As a consequence, the sample microstructure, as observed by SEM, shows a network of small dense zones, including quartz grains, interconnected by recrystallized porous phases. The comparison of material containing the natural kaolinitic clay to material obtained from pure reference minerals underlined the important role of iron impurities in anorthite formation.