Lower stratospheric densities from solar occultation measurements of continuum absorption near 2400/cm

• Published in: Journal of Geophysical Research. D. Atmospheres 2004-01, Vol.109 (D1)
• Main Authors: Rinsland, C P, McHugh, M J, Irion, F W
• Format: Article
• Language: English
• ISSN: 0148-0227
• DOI: 10.1029/2003JD003803

Continuous absorption in the atmospheric window near 2400/cm has been analyzed from infrared solar occultation spectra recorded by the Atmospheric Trace Molecule Spectroscopy (ATMOS) Fourier transform spectrometer at 0.01/cm spectral resolution during its four Shuttle flights between 1985 and 1994. The spring and autumn measurements were recorded over a wide range of temperatures and sulfate aerosol loadings. We used the ratio of the transmissions in microwindows at 2415/cm 2501/cm as a measure of the underlying continuum absorption in the spectra. This ratio decreases from 1.0 to 0.0 as the tangent point density increases from 5 x 10 exp 17 to 100 x 10 exp 17 molecules/cu cm (altitudes 10-30 km). Attenuation in both microwindows is due to overlapping absorptions by the fundamental N2 collision-induced band and distant sub-Lorentzian wings of CO2 lines from the strong nu(sub 3) fundamental band. Optical depths for both N2 and CO2 absorption are proportional to the square of the air density at constant temperature. These microwindows provide high sensitivity to density and low sensitivity to temperature in the lower stratosphere. Stratospheric transmission ratios from all four missions are fitted with a single parameter as a function of tangent point density with a root-mean square residual of about 1 percent. Corresponding densities from this fit agree with ATMOS version 3 densities to about 2.3 percent in the region of good sensitivity at 2 x 10 exp 18 to 8 x 10 exp 18 molecules/cu cm (about 12-20 km altitude). The measured transmission ratio versus density relation has been compared with calculations from temperature-dependent laboratory measurements for both the N2 and CO2 continua. Simulation of the ATMOS spectra based on these laboratory measurements also predict a globally compact relation between the transmission ratio and density but differs from the empirically-determined relation by up to 7 percent in the lower stratosphere.