An ultra-light sustainable sponge for elimination of microplastics and nanoplastics

• Published in: Journal of hazardous materials 2023-08, Vol.456, p.131685-131685, Article 131685
• Main Authors: Fu, Jianxin, Liu, Nuan, Peng, Yunxi, Wang, Guoqing, Wang, Xiaokun, Wang, Qiaoning, Lv, Min, Chen, Lingxin
• Format: Article
• Language: English
• Subjects: Gelatin; Microplastics; Nanoplastics; Plastics; Sponges; Starch; Water; Water Pollutants, Chemical - analysis
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2023.131685

The currently established tools and materials for elimination of the emerging contaminants from environmental and food matrices, particularly micro- and nano-scale plastics, have been largely limited by complicated preparation/operation, high cost, and poor degradability. Here we show that, crosslinking naturally occurring corn starch and gelatin produces ultralight porous sponge upon freeze-drying that can be readily enzymatically decomposed to glucose; The sponge affords capture of micro- and nano-scale plastics into its pores by simple pressing in an efficiency up to 90% while preserving excellent mechanical strength. Heterogeneous diffusion was found to play a dominant role in the adsorption of microplastics by the starch-gelatin sponge. Investigations into the performance of the sponge in complex matrices including tap water, sea water, soil surfactant, and take-out dish soup, further reveal a considerably high removal efficiency (60%∼70%) for the microplastics in the real samples. It is also suggested tiny plastics in different sizes be removable using the sponge with controlled pore size. With combined merits of sustainability, cost-effectiveness, and simple operation without the need for professional background for this approach, industrial and even household removal of tiny plastic contaminants from environmental and food samples are within reach. [Display omitted] •Crosslinking of starch and gelatin can produce ultralight, degradable sponge.•The pores in the sponge afford ∼90% removal efficiency for tiny plastics in water.•As high as 70% microplastics in complex samples can be removed by the sponge.•The present approach is featured with low cost, sustainability and degradability.