Organic Synthesis Using Nitroxides

Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to the thermodynamic stability of these radicals. The presence of bulky N-substituents R1 and R2 prevents nitroxide r...

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Bibliographic Details
Published in:	Chemical reviews 2023-08, Vol.123 (16), p.10302-10380
Main Authors:	Leifert, Dirk, Studer, Armido
Format:	Article
Language:	English
Subjects:	air Alcohols Alkanes ambient temperature Amines Anions biochemistry Bonding strength Cascade chemical reactions Chemical reduction Chemical synthesis cleavage (chemistry) Dimerization Functional groups Materials science Natural products Oxidation Oxidizing agents Physical properties Reagents Reducing agents Room temperature Stability stoichiometry thermodynamics Valence
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