Patterned Adhesion Layer Enables Rugged Pd-MIS Hydrogen Sensors

• Published in: ACS applied materials & interfaces 2023-09, Vol.15 (35), p.41598-41605
• Main Authors: Hood, Ryan, Kolasinski, Robert D., Zutter, Brian, Friddle, Raymond W., Sugar, Joshua D., Bartelt, Norman C., Habermehl, Scott, Whaley, Josh A., Talin, A. Alec
• Format: Article
• Language: English
• Subjects: Functional Inorganic Materials and Devices
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.3c04823

Rugged Pd-metal–insulator–semiconductor (Pd-MIS) hydrogen sensors for detecting charge-exchange particles in fusion reactors have been constructed by utilizing a novel patterned adhesion layer. Poor adhesion at the interface between Pd and SiO2 is a common failure mode for Pd-MIS devices, severely limiting the Pd thickness and their usefulness as hydrogen sensors. The mechanical integrity of the Pd coatings is of particular importance in magnetic fusion energy research where the Pd-MIS diodes are used to measure hydrogen charge-exchange neutral fluence at the wall in tokamaks. In this application, particularly thick Pd contacts are desirable to prevent damage caused by high-energy particles; however, such thick Pd coatings are prone to mechanical failure due to blistering and wire bond detachment during construction or operation. A continuous Ti or Cr adhesion layer is not possible for this application since it would interfere with H uptake at the SiO2 interface, which is essential for the device to generate a response. In this work, we demonstrate that a patterned Cr interlayer substantially improves adhesion while still providing access for hydrogen to reach the SiO2–Pd interface.