Layer interfacing strategy to derive free standing CoFe@PANI bifunctional electrocatalyst towards oxygen evolution reaction and methanol oxidation reaction

• Published in: Journal of colloid and interface science 2024-01, Vol.653, p.949-959
• Main Authors: Rajpure, Manoj M., Jadhav, Harsharaj S., Kim, Hern
• Format: Article
• Language: English
• Subjects: Electrocatalyst; Electrodeposition; Layered double hydroxide; Methanol oxidation reaction; Overpotential; Oxygen evolution reaction
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2023.09.123

The free standing CoFe@PANI bifunctional electrocatalyst display high electrocatalytic activity for OER (overpotential of 230 mV @10 mA cm−2) and MOR (specific current density of 120 mA cm−2) in alkaline medium. [Display omitted] Developing inexpensive, highly electrochemically active, and stable catalysts towards electrochemical studies remains challenge for researchers. In this regard, binder-free CoFe@PANI composite electrocatalyst is deposited on nickel foam (NF) substrate via successive electrodeposition of polyaniline (PANI) and CoFe-LDH at Room temperature (RT). As deposited binder-free CoFe@PANI electrocatalyst displays high electrocatalytic activity towards oxygen evolution reaction (OER) and methanol oxidation reaction (MOR) in alkaline media. In CoFe@PANI structure, interfacing of high-electron conducting PANI establishes strong interconnection with CoFe-LDH by tuning electronic structures, which accelerates the electrochemical performance towards OER and MOR. For OER, CoFe@PANI requires low overpotential (η10) of 237 mV to reach current density (Id) of 10 mA cm−2 and displays low Tafel slope value of 46 mV dec−1 in 1 M KOH solution. Also, it displayed specific Id of 120 mA cm−2, when it was tested for MOR in 1 M KOH with 0.5 M methanol solution. The superior electrocatalytic activity of CoFe@PANI is mainly ascribed to high electrochemical active surface area (ECSA), abundant active sites and fast electron transfer between electrocatalyst and electrode surface. Of note, the current work may open new era for design and development of non-precious highly active and stable hybrid electrocatalysts at RT for various applications.