Conversion of a UO22+ Precursor to UH+ and U+ Using Tandem Mass Spectrometry to Remove Both "yl" Oxo Ligands

Multiple-stage collision-induced dissociation (CID) of a uranyl propiolate cation, [UO2(O2C-C≡CH)]+, can be used to prepare the U-methylidyne species [O═U≡CH]+ [J. Am. Soc. Mass Spectrom. 2019, 30, 796-805]. Here, we report that CID of [O═U≡CH]+ causes elimination of CO to create [UH]+, followed by...

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Bibliographic Details
Published in:Journal of the American Society for Mass Spectrometry 2023-10, Vol.34 (11), p.2439-2442
Main Authors: Terhorst, Justin G, Corcovilos, Theodore A, van Stipdonk, Michael J
Format: Article
Language:English
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