Sequestration of Ni (II), Pb (II), and Zn (II) utilizing biogenic synthesized Fe3O4/CLPC NCs and modified Fe3O4/CLPC@CS NCs: Process optimization, simulation modeling, and feasibility study

• Published in: Environmental science and pollution research international 2023-11, Vol.30 (53), p.114056-114077
• Main Authors: Chander, Subhash, Yadav, Sangita, Gupta, Asha, Luhach, Neha
• Format: Article
• Language: English
• Subjects: Adsorption; Aquatic Pollution; Aqueous solutions; Atmospheric Protection/Air Quality Control/Air Pollution; Chemisorption; Citrus limetta; Correlation coefficient; Correlation coefficients; Earth and Environmental Science; Ecotoxicology; Electroplating; Environment; Environmental Chemistry; Environmental Health; Feasibility studies; Functional groups; Heavy metals; Industrial wastewater; Iron oxides; Magnetite; Metal ions; Nanocomposites; Research Article; Surface chemistry; Synthesis; Waste Water Technology; Water Management; Water Pollution Control; Zinc
• ISSN: 1614-7499; 0944-1344; 1614-7499
• DOI: 10.1007/s11356-023-30318-w

The present study reports low-cost novel biogenic magnetite Citrus limetta peels carbon (Fe 3 O 4 /CLPC) nanocomposites and modified Fe 3 O 4 /CLPC@CS nanocomposites cross-linked with glutaraldehyde and subsequently employed in batch mode sequestration of heavy metals ions. Diverse techniques fully characterized them, and the influence of operating variables on adsorption reactions from aqueous solutions was investigated. The Brunauer, Emmett, and Teller (BET) surface areas of synthesized Fe 3 O 4 /CLPC and Fe 3 O 4 /CLPC@CS NCs were 53.91 and 32.16 m 2 /g, while the mesoporous diameters were 7.69 and 7.57 nm, respectively. The Langmuir isotherm and Pseudo second order kinetic were well-fitting and capable of explaining the adsorption reaction. The Langmuir-based monolayer adsorption ( q max ) for Fe 3 O 4 /CLPC@CS NCs was 82.65, 95.24, and 64.10 mg/g, higher than Fe 3 O 4 /CLPC NCs, which were 70.92, 84.75, and 59.17 mg/g for Ni (II), Pb (II), and Zn (II), respectively. Each metal's pseudo second order correlation coefficient ( R 2  ≥ 0.99) reveals that nanocomposites surface binding functional groups controlled the adsorption rate via chemisorption. Further, thermodynamic results confirm that each studied metal ions' adsorption was spontaneous, endothermic, and characterized by an increase in randomness. In addition to magnetic separability, three ad-desorption cycles yielded exceptional adsorption efficacy and > 93% regenerability. The present study also reveals the effective utilization of Fe 3 O 4 /CLPC and Fe 3 O 4 /CLPC@CS NCs as cost-effective magnetic separable green adsorbents for heavy metals sequestration from electroplating wastewater. Graphical Abstract