Adsorption of trace heavy metals through organic compounds enriched biochar using isotherm adsorption and kinetic models

• Published in: Environmental research 2024-01, Vol.241, p.117702-117702, Article 117702
• Main Authors: Dad, Fiza Pir, Khan, Waqas-ud-Din, Sharif, Faiza, Nizami, Abdul Sattar
• Format: Article
• Language: English
• Subjects: adsorbents; adsorption; Adsorption isotherm; alanine; aqueous solutions; Biochar; chromium; copper; ecosystems; Environmental management; Glycine; Kinetic modelling; kinetics; lead; nickel; Organic compounds; rice hulls; sorption isotherms
• ISSN: 0013-9351; 1096-0953
• DOI: 10.1016/j.envres.2023.117702

Trace heavy metals such as copper and nickel, when exceeds a certain level, cause detrimental effects on the ecosystem. The current study examined the potential of organic compounds enriched rice husk biochar (OCEB's) to remove the trace heavy metals from an aqueous solution in four steps. In 1st step, biochar’ physical and chemical properties were analyzed through scanning electron microscope (SEM) and Fourier transforms infrared spectroscopy (FTIR). In the 2nd step, two biochar vis-a-vis glycine, alanine enriched biochar (GBC, ABC) was selected based on their adsorption capacity of four different metals Cr, Cu, Ni and Pb (chromium, copper, nickel, and lead). These two adsorbents (GBC, ABC) were further used to evaluate the best interaction of biochar for metal immobilization based on varying concentrations and times. Langmuir isotherm model suggested that the adsorption of Ni and Cu on the adsorbent surface supported the monolayer sorption. The qmax value of GBC for Cu removal increased by 90% compared to SBC (Simple rice husk biochar). The interaction of Cu and Ni with GBC and ABC was chemical, and 10 different time intervals were studied using pseud first and second-order kinetics models. The current study has supported the pseudo second-order kinetic model, which exhibited that the sorption of Ni and Cu occurred due to the chemical processes. The % removal efficiency with GBC was enhanced by 21% and 30% for Cu and Ni, respectively compared to the SBC. It was also noticed that GBC was 21% more efficient for % removal efficiency than the CBC. The study's findings supported that organic compound enriched rice husk biochar (GBC and ABC) is better than SBC for immobilizing the trace heavy metals from an aqueous solution. [Display omitted] •Glycine and Alanine enriched biochar are excellent metal adsorbents.•Cu was significantly removed (97% and 96%) from the aqueous solution by GBC and ABC.•Chemical reaction was involved between organic compounds enriched biochar and heavy metals.•Organic compounds enriched biochar may serve to deal with the issue of heavy metal-contaminated water.•Limitations for metals in extreme environments should examine organic compounds enriched biochar.