Methane absorption in the atmosphere of Jupiter from 1800 to 9500 cm −1 and implications for vertical cloud structure

• Published in: Icarus (New York, N.Y. 1962) N.Y. 1962), 2005-08, Vol.176 (2), p.255-271
• Main Authors: Irwin, P.G.J., Sihra, K., Bowles, N., Taylor, F.W., Calcutt, S.B.
• Format: Article
• Language: English
• Subjects: Astronomy; Atmosphere; Earth, ocean, space; Exact sciences and technology; Jupiter; Radiative transfer; Solar system
• ISSN: 0019-1035; 1090-2643
• DOI: 10.1016/j.icarus.2005.02.004

New measurements of the low-temperature near-infrared absorption of methane (Sihra, 1998, Laboratory measurements of near-infrared methane bands for remote sensing of the jovian atmosphere, Ph.D. thesis, University of Oxford) have been combined with existing, longer path-length, higher-temperature data of Strong et al. (1993, Spectral parameters of self- and hydrogen-broadened methane from 2000 to 9500 cm −1 for remote sounding of the atmosphere of Jupiter, J. Quant. Spectrosc. Radiat. Trans. 50, 309–325) and fitted with band models. The combined data set is found to be more consistent with previous low-temperature methane absorption measurements than that of Strong et al. (1993, J. Quant. Spectrosc. Radiat. Trans. 50, 309–325) but covers the same wider wavelength range and accounts for both self- and hydrogen-broadening conditions. These data have been fitted with k-coefficients in the manner described by Irwin et al. (1996, Calculated k-distribution coefficients for hydrogen- and self-broadened methane in the range 2000–9500 cm −1 from exponential sum fitting to band modelled spectra, J. Geophys. Res. 101, 26,137–26,154) and have been used in multiple-scattering radiative transfer models to assess their impact on our previous estimates of the jovian cloud structure obtained from Galileo Near-Infrared Mapping Spectrometer (NIMS) observations (Irwin et al., 1998, Cloud structure and atmospheric composition of Jupiter retrieved from Galileo NIMS real-time spectra, J. Geophys. Res. 103, 23,001–23,021; Irwin et al., 2001, The origin of belt/zone contrasts in the atmosphere of Jupiter and their correlation with 5-μm opacity, Icarus 149, 397–415; Irwin and Dyudina, 2002, The retrieval of cloud structure maps in the equatorial region of Jupiter using a principal component analysis of Galileo/NIMS data, Icarus 156, 52–63). Although significant differences in methane opacity are found at cooler temperatures, the difference in the optical depth of the atmosphere due to methane is found to diminish rapidly with increasing pressure and temperature and thus has negligible effect on the cloud structure inferred at deeper levels. Hence the main cloud opacity variation is still found to peak at around 1–2 bar using our previous analytical approach, and is thus still in disagreement with Galileo Solid State Imager (SSI) determinations (Banfield et al., 1998, Jupiter's cloud structure from Galileo imaging data, Icarus 135, 230–250; Simon-Miller et al., 2001, Color and the