Active Site Engineering and Theoretical Aspects of “Superhydrophilic” Nanostructure Array Enabling Efficient Overall Water Electrolysis

• Published in: Small (Weinheim an der Bergstrasse, Germany) Germany), 2023-12, Vol.19 (50), p.e2304143-n/a
• Main Authors: Barik, Sidharth, Kharabe, Geeta Pandurang, Illathvalappil, Rajith, Singh, Chandrodai Pratap, Kanheerampockil, Fayis, Walko, Priyanka S., Bhat, Suresh K., Devi, R. Nandini, Vinod, C. P, Krishnamurty, Sailaja, Kurungot, Sreekumar
• Format: Article
• Language: English
• Subjects: Density functional theory; density functional theory (DFT) study; Electrocatalysts; Electrode materials; Electrodes; Electrolysis; Green hydrogen; hydrogen evolution reaction (HER); Hydrogen evolution reactions; Hydrogen production; hydrothermal synthesis; Metal foams; Molybdates; Nanostructure; Nanotechnology; Nickel compounds; Noble metals; oxygen evolution reaction (OER); Oxygen evolution reactions; superhydrophilic nanostructures; synergistic interaction; water electrolysis; Water splitting
• ISSN: 1613-6810; 1613-6829
• DOI: 10.1002/smll.202304143

The rational design of noble metal‐free electrocatalysts holds great promise for cost‐effective green hydrogen generation through water electrolysis. In this context, here, the development of a superhydrophilic bifunctional electrocatalyst that facilitates both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in alkaline conditions is demonstrated. This is achieved through the in situ growth of hierarchical NiMoO4@CoMoO4·xH2O nanostructure on nickel foam (NF) via a two‐step hydrothermal synthesis method. NiMoO4@CoMoO4·xH2O/NF facilitates OER and HER at the overpotentials of 180 and 220 mV, respectively, at the current density of 10 mA cm−2. The NiMoO4@CoMoO4·xH2O/NF ǁ NiMoO4@CoMoO4·xH2O/NF cell can be operated at a potential of 1.60 V compared to 1.63 V displayed by the system based on the Pt/C@NFǁRuO2@NF standard electrode pair configuration at 10 mA cm−2 for overall water splitting. The density functional theory calculations for the OER process elucidate that the lowest ΔG of NiMoO4@CoMoO4 compared to both Ni and NiMoO4 is due to the presence of Co in the OER catalytic site and its synergistic interaction with NiMoO4. The preparative strategy and mechanistic understanding make the windows open for the large‐scale production of the robust and less expensive electrode material for the overall water electrolysis. In this article, the development of a superhydrophilic bifunctional electrocatalyst by in situ growth of the hierarchical NiMoO4@CoMoO4·xH2O nanostructure on nickel foam (NF) via two‐step hydrothermal synthesis method is demonstrated. The CoMoO4 nanoparticle decoration on NiMoO4·xH2O nanorods makes the electrode more process‐friendly and contributes to achieving improved activity as well as better long‐term stability during the overall water‐splitting process.