Aluminium 8-Hydroxyquinolinate N-Oxide as a Precursor to Heterometallic Aluminium–Lanthanide Complexes

A reaction in anhydrous toluene between the formally unsaturated fragment [Ln(hfac)3] (Ln3+ = Eu3+, Gd3+ and Er3+; Hhfac = hexafluoroacetylacetone) and [Al(qNO)3] (HqNO = 8-hydroxyquinoline N-oxide), here prepared for the first time from [Al(OtBu)3] and HqNO, affords the dinuclear heterometallic com...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2024-01, Vol.29 (2), p.451
Main Authors: Gallo, Elisa, Bellucci, Luca, Carlotto, Silvia, Bottaro, Gregorio, Babetto, Luca, Giordano, Luca, Marchetti, Fabio, Samaritani, Simona, Armelao, Lidia, Labella, Luca
Format: Article
Language:English
Subjects:
8-hydroxyquinoline N-oxide
aluminium
Geometry
heterometallic complexes
Hydrogen bonds
lanthanides
Ligands
Metals
quantum mechanical calculations
Single crystals
X-ray structure
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