Consolidation of a Cu-2.5 vol. % Al2O3 powder using high energy mechanical milling

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2005-11, Vol.410, p.375-380
• Main Authors: Zhang, D L, Raynova, S, Koch, C C, Scattergood, R O, Youssef, K M
• Format: Article
• Language: English
• ISSN: 0921-5093
• DOI: 10.1016/j.msea.2005.08.109

In situ consolidation of a Cu-2.5 vol.% Al2O3 powder by high energy ball milling has been studied by examining changes of size, morphology, macrostructure and microstructure of the powder particles, lumps, and balls formed with increasing milling time under different conditions. This study clearly demonstrates that the consolidation of the Cu-2.5 vol.% Al2O3 powder by high energy ball milling is accomplished initially by coalescence of powder particles through cold welding which leads to formation of lumps, then by cold welding and re-shaping of the lumps into small balls, and finally by cold welding of small balls into larger balls. The maximum diameter of the large balls is comparable with the diameter of the milling balls used as a milling medium. The two types of defects in the consolidated lumps and balls in the large balls, concentrated voids and crack-like voids, show that the material undergoes a large amount of plastic flow during the process of consolidation. The consolidation of the Cu-2.5 vol.% Al2O3 powder can also been achieved by a combination of cryomilling and room temperature milling, but the consolidation process is slower due to increased hardness of the powder particles. The study also shows that the Al2O3 fine particles are incorporated into the Cu matrix forming a composite structure when the lumps are formed, and the large balls exhibit a nanostructure with grain sizes smaller than 100 nm.