Identification of arsenato antimonates in copper anode slimes

• Published in: Hydrometallurgy 2006-11, Vol.84 (3), p.211-217
• Main Authors: WANG, Xue-Wen, CHEN, Qi-Yuan, YIN, Zhou-Lan, XIAO, Lian-Sheng
• Format: Article
• Language: English
• Subjects: Applied sciences; Arsenato antimonate; Arsenato antimonic acid; Copper electrorefining; Exact sciences and technology; Metals. Metallurgy; Production of metals; Solution purification
• ISSN: 0304-386X; 1879-1158
• DOI: 10.1016/j.hydromet.2006.05.013

It was found that, in copper electrolyte, the combination of As(V) and Sb(V) can form arsenato antimonic acid (AAAc) and, the reactions of AAAc with As(III), Sb(III), and Bi(III) can produce the precipitates of arsenato antimonates. During copper electrorefining, the As, Sb, and Bi deposited into the anode slime from the electrolyte are dominant in the forms of arsenato antimonates. It is extremely difficult to separate pure arsenato antimonates from copper anode slimes, while it is easy to synthesize arsenato antimonates using H 2O 2 to oxidize As(III) and Sb(III) in copper refining electrolyte. The composition and structure of the arsenato antimonates were determined with chemical analysis, IR and XRD techniques. The characteristic bands in the IR spectra of arsenato antimonates are δ of As–OH and Sb–OH at 1126.8 cm − 1 , ν as of As–OH at 1029.7 cm − 1 , ν as of As–OX(X = As, Sb) at 819.5 cm − 1 , ν as of Sb–OH at 618.4 cm − 1 , ν as of Sb–OY(Y = As, Sb) at 507.2 cm − 1 , and ν as of Sb–OBi at 470 cm − 1 . The arsenato antimonates form irregular masses of amorphous structure because there are many OH groups in AAAc, the OH groups bond with As(III), Sb(III), and Bi(III) at random, which makes the arsenato antimonates formed in copper refining electrolyte have no fixed ratios for As/Sb/Bi. The formation of the arsenato antimonates can be expressed as follows: aH 3AsO 4 + bH[Sb(OH) 6] + cMeO + →Me c As a Sb b O (3 a+5 b+ c/2+1) H ( a+5 b−2 c+2) · xH 2O + cH + + ( a + b + c / 2 − 1 − x)H 2O, where Me = As(III), Sb(III) and Bi(III); a ≥ 1, b ≥ 1, c ≤ (3 a + b)