Interfacial Engineering of Zn Metal via a Localized Conjugated Layer for Highly Reversible Aqueous Zinc Ion Battery

• Published in: Angewandte Chemie International Edition 2024-04, Vol.63 (14), p.e202319091-n/a
• Main Authors: Liu, Zhenjie, Li, Guanjie, Xi, Murong, Huang, Yudai, Li, Haobo, Jin, Huanyu, Ding, Juan, Zhang, Shilin, Zhang, Chaofeng, Guo, Zaiping
• Format: Article
• Language: English
• Subjects: Adhesive strength; Anodes; aqueous zinc ion batteries; cyclization of polyacrylonitrile; Deposition; Durability; Energy storage; Hydrogen evolution; Lewis acid; Polyacrylonitrile; Polymers; Protons; Rechargeable batteries; Side reactions; Storage systems; Zinc; zinc ion conductor; Zn anode
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.202319091

Aqueous zinc‐ion batteries are regarded as promising and efficient energy storage systems owing to remarkable safety and satisfactory capacity. Nevertheless, the instability of zinc metal anodes, characterized by issues such as dendrite growth and parasitic side reactions, poses a significant barrier to widespread applications. Herein, we address this challenge by designing a localized conjugated structure comprising a cyclic polyacrylonitrile polymer (CPANZ), induced by a Zn2+‐based Lewis acid (zinc trifluoromethylsulfonate) at a temperature of 120 °C. The CPANZ layer on the Zn anode, enriched with appropriate pyridine nitrogen‐rich groups (conjugated cyclic −C=N−), exhibits a notable affinity for Zn2+ with ample deposition sites. This zincophilic skeleton not only serves as a protective layer to guide the deposition of Zn2+ but also functions as proton channel blocker, regulating the proton flux to mitigate the hydrogen evolution. Additionally, the strong adhesion strength of the CPANZ layer guarantees its sustained protection to the Zn metal during long‐term cycling. As a result, the modified zinc electrode demonstrates long cycle life and high durability in both half‐cell and pouch cells. These findings present a feasible approach to designing high performance aqueous anodes by introducing a localized conjugated layer. A polyacrylonitrile‐based zinc ion conductor (CPANZ) with a localized conjugated structure is induced and achieved at low temperature by Lewis acidic Zn(OTf)2. The CPANZ layer effectively accelerates the Zn2+ migration but restricts the H+ migration. Encouragingly, the chemical corrosion, hydrogen evolution reaction and other side reactions are significantly mitigated at the CPANZ@Zn anode and homogeneous Zn deposition/dissolution is guaranteed.