Cation/Anion-Dual regulation in Na3MnTi(PO4)3 cathode achieves the enhanced electrochemical properties of Sodium-Ion batteries

• Published in: Journal of colloid and interface science 2024-06, Vol.664, p.381-388
• Main Authors: Li, Shu-Ying, Yin, Qi-Min, Gu, Zhen-Yi, Liu, Yan, Liu, Yan-Ning, Su, Meng-Yuan, Wu, Xing-Long
• Format: Article
• Language: English
• Subjects: Dual regulation; Na3MnTi(PO4)3; NASICON; Phosphate cathode; Sodium-ion batteries
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2024.03.048

In this study, the electrochemical performance of Na3MnTi(PO4)3 material has been improved through cation/anion-dual regulation. This dual regulation provides a strategy for phosphate materials as an advanced cathode for sodium-ion batteries. [Display omitted] Na3MnTi(PO4)3 (NMTP) emerges as a promising cathode material with high-performance for sodium-ion batteries (SIBs). Nevertheless, its development has been limited by several challenges, including poor electronic conductivity, the Mn3+ Jahn-Teller effect, and the presence of a Na+/Mn2+ cation mixture. To address these issues, we have developed a cation/anion-dual regulation strategy to activate the redox reactions involving manganese, thereby significantly enhancing the performance of NMTP. This strategy simultaneously enhances the structural dynamics and facilitates rapid ion transport at high rates by inducing the formation of sodium vacancy. The combined effects of these modifications lead to a substantial improvement in specific capacity (79.1 mAh/g), outstanding high-rate capabilities (35.9 mAh/g at 10C), and an ultralong cycle life (only 0.040 % capacity attenuation per cycle over 250 cycles at 1C for Na3.34Mn1.2Ti0.8(PO3.98F0.02)3) when used as a cathode material in SIBs. Furthermore, its performance in full cell demonstrates impressive rate capability (44.4 mAh/g at 5C) and exceptional cycling stability (with only 0.116 % capacity decay per cycle after 150 cycles at 1C), suggesting its potential for practical applications. This work presents a dual regulation strategy targeting different sites, offering a significant advancement in the development of NASICON phosphate cathodes for SIBs.