Constant Current Electrophoretic Infiltration Deposition of Fiber-Reinforced Ceramic Composites

Modified electrophoretic infiltration deposition (EPID) under constant current conditions is used to fabricate non‐conductive‐fiber‐reinforced composites from an ethanol suspension. Particles are infiltrated through a fiber preform by an electric field and are deposited on the front of the electrode...

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Bibliographic Details
Published in:Journal of the American Ceramic Society 2007-04, Vol.90 (4), p.1063-1070
Main Authors: Bao, Yahua, Nicholson, Patrick S.
Format: Article
Language:English
Subjects:
Applied sciences
Building materials. Ceramics. Glasses
Capillarity
Ceramic industries
Ceramics
Cermets, ceramic and refractory composites
Charged particles
Chemical industry and chemicals
Cross-disciplinary physics: materials science
rheology
Deposition
Deposits
Electric fields
Electrophoresis
Exact sciences and technology
Fiber preforms
Infiltration
Materials science
Nanoparticles
Other materials
Particulate composites
Physics
Solution chemistry
Specific materials
Structural ceramics
Technical ceramics
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Summary:Modified electrophoretic infiltration deposition (EPID) under constant current conditions is used to fabricate non‐conductive‐fiber‐reinforced composites from an ethanol suspension. Particles are infiltrated through a fiber preform by an electric field and are deposited on the front of the electrode and “backfill” through the fiber preform. A uniform morphology is achieved at the optimum deposition rate. The constant current EPID process is modeled as capillary infiltration electrophoresis. Particles “stream” the fiber preform due to the repulsive interaction between the fiber filaments and the particles as both have the same‐sign surface charge. Electro‐osmotic flow makes no contribution to deposit yield as the net flow across a closed capillary cross section is zero. Hamaker's law is extended to electrophoretic infiltration; however, the total deposit yield is controlled by particle electrophoresis outside the capillaries due to the much lower electric field in the suspension. The deposit thickness increases linearly with time under optimum current conditions. Too high a deposition rate promotes air entrapment in the depositing green body.
ISSN:0002-7820
1551-2916
DOI:10.1111/j.1551-2916.2007.01504.x