Circular economical approach of extracting nanocarbons from waste pea peel for sensing of p-nitrophenol and its conversion into paracetamol

• Published in: Chemosphere (Oxford) 2024-05, Vol.356, p.141930-141930, Article 141930
• Main Authors: Laddha, Harshita, Yadav, Priya, Sharma, Priya, Agarwal, Madhu, Gupta, Ragini
• Format: Article
• Language: English
• Subjects: Acetaminophen - analysis; Acetaminophen - chemistry; Aminophenols; Biowaste valorization; Carbon - chemistry; Catalysis; Charcoal - chemistry; Circular economy; Nanostructures - chemistry; Nitrophenols - chemistry; p-nitrophenol; Paracetamol; Pisum sativum - chemistry; Quantum Dots - chemistry; Waste pea peels
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2024.141930

An important paradigm shift towards the circular economy is to prioritize waste prevention, reuse, recycling, and recovery before disposal is necessary. In this context, a sustainable protocol of converting waste pea peel (wPP) into low-cost carbon nanomaterials for sensing and conversion of p-nitrophenol (p-NP) into value-added paracetamol is being reported. Two fractions of the carbonaceous nanomaterials were obtained after the hydrothermal treatment (HT) of wPP, firstly an aqueous portion containing water-soluble carbon dots (wPP-CDs) and a solid residue, which was converted into carbonized biochar (wPP-BC). Blue-colored fluorescent wPP-CDs displayed excitation-dependent and pH-independent properties with a quantum yield (QY) of 8.82 %, which were exploited for the fluorescence sensing of p-NP with 4.20 μM limit of detection. Pyrolyzed biochar acting as an efficient catalyst effectively reduces p-NP to p-aminophenol (p-AP) in just 16 min with a 0.237 min−1 rate of conversion. Furthermore, the produced p-AP was converted into paracetamol, an analgesic and antipyretic drug, to achieve zero waste theory. Thus, this study provides the execution of sustainable approaches based on the integral valorization of biowaste that can be further recycled and reused, offering an effective way to attain a profitable circular economy. [Display omitted] •Value-added carbon nanomaterials were synthesized from waste pea peels.•Blue fluorescent carbon dots act as a fluorescent sensor for p-nitrophenol (p-NP).•Solid biochar serves as a promising catalyst for the efficient reduction of p-NP.•The obtained p-aminophenol was further converted into a valuable drug, paracetamol.