Halogen-Decorated Metal–Organic Frameworks for Efficient and Selective CO2 Capture, Separation, and Chemical Fixation with Epoxides under Mild Conditions

• Published in: ACS applied materials & interfaces 2024-04, Vol.16 (16), p.20626-20641
• Main Authors: Karmakar, Anirban, Santos, Andreia A. C. D., Pagliaricci, Noemi, Pires, João, Batista, Mary, Alegria, Elisabete C. B. A., Martin-Calvo, Ana, Gutiérrez-Sevillano, Juan José, Calero, Sofia, Guedes da Silva, M. Fátima C., Pettinari, Riccardo, Pombeiro, Armando J. L.
• Format: Article
• Language: English
• Subjects: Energy, Environmental, and Catalysis Applications
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.4c02560

In the present work, three novel halogen-appended cadmium­(II) metal–organic frameworks [Cd2(L1)2(4,4′-Bipy)2] n ·4n(DMF) (1), [Cd2(L2)2(4,4′-Bipy)2] n ·3n(DMF) (2), and [Cd­(L3)­(4,4′-Bipy)] n ·2n(DMF) (3) [where L1 = 5-{(4-bromobenzyl)­amino}­isophthalate; L2 = 5-{(4-chlorobenzyl)­amino}­isophthalate; L3 = 5-{(4-fluorobenzyl)­amino}­isophthalate; 4,4′-Bipy = 4,4′-bipyridine; and DMF = N,N′-dimethylformamide] have been synthesized under solvothermal conditions and characterized by various analytical techniques. The single-crystal X-ray diffraction analysis demonstrated that all the MOFs feature a similar type of three-dimensional structure having a binuclear [Cd2(COO)4(N)4] secondary building block unit. Moreover, MOFs 1 and 2 contain one-dimensional channels along the b-axis, whereas MOF 3 possesses a 1D channel along the a-axis. In these MOFs, the pores are decorated with multifunctional groups, i.e., halogen and amine. The gas adsorption analysis of these MOFs demonstrate that they display high uptake of CO2 (up to 5.34 mmol/g) over N2 and CH4. The isosteric heat of adsorption (Q st) value for CO2 at zero loadings is in the range of 18–26 kJ mol–1. In order to understand the mechanism behind the better adsorption of CO2 by our MOFs, we have also performed configurational bias Monte Carlo simulation studies, which confirm that the interaction between our MOFs and CO2 is stronger compared to those with N2 and CH4. Various noncovalent interactions, e.g., halogen (X)···O, Cd···O, and O···O, between CO2 and the halogen atom, the Cd­(II) metal center, and the carboxylate group from the MOFs are observed, respectively, which may be a reason for the higher carbon dioxide adsorption. Ideal adsorbed solution theory (IAST) calculations of MOF 1 demonstrate that the obtained selectivity values for CO2/CH4 (50:50) and CO2/N2 (15:85) are ca. 28 and 193 at 273 K, respectively. However, upon increasing the temperature to 298 K, the selectivity value (S = 34) decreases significantly for the CO2/N2 mixture. We have also calculated the breakthrough analysis curves for all the MOFs using mixtures of CO2/CH4 (50:50) and CO2/N2 (50:50 and 15:85) at different entering gas velocities and observed larger retention times for CO2 in comparison with other gases, which also signifies the stronger interaction between our MOFs and CO2. Moreover, due to the presence of Lewis acidic metal centers, these MOFs act as heterogeneous catalysts for the CO2 fixation reactions with different