Optimizing in-situ CO2 mineralisation: geomechanics and scalability in dunite and serpentinite rocks – Examples from Australia and New Zealand

• Published in: The Science of the total environment 2024-06, Vol.927, p.172277-172277, Article 172277
• Main Authors: Al Kalbani, Muhannad, Serati, Mehdi, Hofmann, Harald, Ritchie, Tom, Bore, Thierry
• Format: Article
• Language: English
• Subjects: Australia; Basalt; Climate change; CO2 mineralisation; Enhanced mineralisation; Ex-situ; Fracturing; In-situ mineralisation; Mineralisation; New Zealand; Peridotite; Serpentinite; Ultramafic
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2024.172277

The collective drive towards achieving net-zero greenhouse gas emissions by 2050 has spurred interest in engineering solutions for carbon capture and storage worldwide. One such approach involves the permanent storage of CO2 in earth-abundant Ca-, Fe-, and Mg-bearing silicate rocks and minerals as carbonates via the process of CO2 mineralisation. This necessitates a thorough understanding of carbonate conversion under geologically relevant conditions. Nevertheless, research on CO2 injection for mineralisation via naturally fractured host rocks or induced fractures, with a research emphasis on rock mechanics and stimulated reservoir volumes (SRV) within geoengineering CO2 storage, is continuously expanding. This research addresses critical challenges related to identifying favourable geographic locations for CO2 mineralisation. It specifically focuses on the abundant availability of Mg, Ca, and Fe cations for exothermic CO2 reactions and their impact on fracture conductivity during in-situ mineralisation. A comprehensive analysis of 26 dunite and serpentinite samples from diverse locations in Australia and New Zealand, including 10 from a cored drilled hole, was conducted. Quantification of divalent cation (Mg, Ca, Fe) content and cation release capacity using XRF and XRD revealed higher cation percentages in dunite samples (approximately 30 %) compared to serpentinite samples (approximately 26 %). Additionally, the study estimated the stimulated rock mass-to-CO2 sequestered ratio, RCO2, with dunite samples averaging approximately 2.20 RCO2 values and serpentinite samples averaging approximately 2.53. Geomechanical testing enabled the prediction of fracture propagation pressures during aqueous CO2 injection for in-situ mineralisation and the estimation of fracture geometries, emphasizing the role of rock stiffness in determining fracture width (averaging 6.0 mm). Furthermore, the research estimated the rock volume exposed to CO2-laden fluid during injection, particularly focusing on the GHQ-3 sample, which theoretically amounted to approximately 600 kg of rock capable of sequestering around 300 kg of CO2 for a 10 m3 fluid volume with a CO2 concentration of 1molkg−1. The study established a relationship between injected volume and CO2 uptake, suggesting the potential for significant CO2 sequestration scalability by employing horizontal wells and fracturing additional zones, thereby creating and intersecting multiple transverse fractures along a single target