Synthesis of Polycyclic n/5/8 and n/5/5/5 Skeletons Using Rhodium-Catalyzed [5 + 2 + 1] Cycloaddition of Exocyclic-ene-vinylcyclopropanes and Carbon Monoxide

A rhodium-catalyzed [5 + 2 + 1] reaction of exocyclic-ene-vinylcyclopropanes (exo-ene-VCPs) and CO has been realized to access challenging tricyclic n/5/8 skeletons (n = 5, 6, 7), some of which are found in natural products. This reaction can be used to build tetracyclic n/5/5/5 skeletons (n = 5, 6)...

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Bibliographic Details
Published in:Organic letters 2023-03, Vol.25 (10), p.1732-1736
Main Authors: Wang, Lu-Ning, Huang, Zhiqiang, Yu, Zhi-Xiang
Format: Article
Language:English
Subjects:
carbon monoxide
chemical structure
cycloaddition reactions
skeleton
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