SnO2 Interacted with Sodium Thiosulfate for Perovskite Solar Cells over 25% Efficiency

• Published in: The journal of physical chemistry letters 2024-06, Vol.15 (22), p.5854-5861
• Main Authors: Xia, Tianyu, Ouyang, Yunfei, Wang, Can, Pan, Yi, Gao, Qin, Chen, Xiao, Zhang, Bo, Chen, Kun, He, Zijuan, Yuan, Xiangbao, Shen, Chengxia, Guo, Bing, Deng, Yehao, Chen, Shijian, Jiang, Tingming, Sun, Kuan
• Format: Article
• Language: English
• Subjects: Physical Insights into Chemistry, Catalysis, and Interfaces
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.4c01022

Tin oxide (SnO2) as electron transportation layer (ETL) has demonstrated remarkable performance applied in perovskite solar cells but still accommodated a host of defects such as oxygen vacancies, uncoordinated Sn4+ , and absorbed hydroxyl groups. Here, we use inorganic sodium thiosulfate Na2S2O3 to modify SnO2 nanoparticles in a bulk blending manner. Strong interaction between Na2S2O3 and SnO2 occurs, as reflected from the elemental chemical state change. The interaction has endowed the SnO2 film with better uniformity, increased conductivity, and more matched energy level with perovskite. Moreover, the modified SnO2 film as a substrate could promote the crystallization of perovskite by suppressing unreacted residual PbI2. The trap density from perovskite bulk to the SnO2 film across their interface has been effectively reduced, thus inhibiting the nonradiative recombination and promoting the transportation and extraction of charge carriers. Finally, the solar cell based on modified SnO2 has achieved a champion efficiency of 25.2%, demonstrating the effectiveness and potential of sulfur-containing molecules on optimizing the SnO2 property.