Lysine-mediated surface modification of cellulose nanocrystal films for multi-channel anti-counterfeiting

• Published in: Carbohydrate polymers 2024-09, Vol.340, p.122315-122315, Article 122315
• Main Authors: Hu, Songnan, Yue, Fengxia, Peng, Fang, Zhou, Xin, Chen, Yian, Song, Tao, Qi, Haisong
• Format: Article
• Language: English
• Subjects: Anti-counterfeiting; Cellulose nanocrystal; Fluorescent; Structural colors; Surface modification
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2024.122315

Utilizing advanced multiple channels for information encryption offers a powerful strategy to achieve high-capacity and highly secure data protection. Cellulose nanocrystals (CNCs) offer a sustainable resource for developing information protection materials. In this study, we present an approach that is easy to implement and adapt for the covalent attachment of various fluorescence molecules onto the surface of CNCs using the Mannich reaction in aqueous-based medium. Through the use of the Mannich reaction-based surface modification technique, we successfully achieved multi-color fluorescence in the resulting CNCs. The resulting CNC derivatives were thoroughly characterized by two dimensional heteronuclear single quantum coherence nuclear magnetic resonance (2D HSQC NMR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron (XPS) spectroscopy. Notably, the optical properties of CNCs were well maintained after modification, resulting in films exhibiting blue and red structural colors. This enables the engineering of highly programmable and securely encoded anti-counterfeit labels. Moreover, subsequent coating of the modified CNCs with MXene yielded a highly secure encrypted matrix, offering advanced security and encryption capabilities under ultraviolet, visible, and near-infrared wavelengths. This CNC surface-modification enables the development of multimodal security labels with potential applications across various practical scenarios. [Display omitted]