Reaction Kinetics of CH2OO and syn-CH3CHOO Criegee Intermediates with Acetaldehyde

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2024-06, Vol.128 (25), p.4956-4965
• Main Authors: Jiang, Haotian, Liu, Yue, Xiao, Chunlei, Yang, Xueming, Dong, Wenrui
• Format: Article
• Language: English
• Subjects: A: Structure, Spectroscopy, and Reactivity of Molecules and Clusters
• ISSN: 1089-5639; 1520-5215; 1520-5215
• DOI: 10.1021/acs.jpca.4c01374

Criegee intermediates exert a crucial influence on atmospheric chemistry, functioning as powerful oxidants that facilitate the degradation of pollutants, and understanding their reaction kinetics is essential for accurate atmospheric modeling. In this study, the kinetics of CH2OO and syn-CH3CHOO reactions with acetaldehyde (CH3CHO) were investigated using a flash photolysis reaction tube coupled with the OH laser-induced fluorescence (LIF) method. The experimental results indicate that the reaction of syn-CH3CHOO with CH3CHO is independent of pressure in the range of 5–50 Torr when using Ar as the bath gas. However, the rate coefficient for the reaction between CH2OO and CH3CHO at 5.5 Torr was found to be lower compared to the near-constant values observed between 10 and 100 Torr. Furthermore, the reaction of syn-CH3CHOO with CH3CHO demonstrated positive temperature dependence from 283 to 330 K, with a rate coefficient of (2.11 ± 0.45) × 10–13 cm3 molecule–1 s–1 at 298 K. The activation energy and pre-exponential factor derived from the Arrhenius plot for this reaction were determined to be 2.32 ± 0.49 kcal mol–1 and (1.66 ± 0.61) × 10–11 cm3 molecule–1 s–1, respectively. In comparison, the reaction of CH2OO with CH3CHO exhibited negative temperature dependence, with a rate coefficient of (2.16 ± 0.39) × 10–12 cm3 molecule–1 s–1 at 100 Torr and 298 K and an activation energy and a pre-exponential factor of −1.73 ± 0.31 kcal mol–1 and (1.15 ± 0.21) × 10–13 cm3 molecule–1 s–1, respectively, over the temperature range of 280–333 K.