Dual Function of Hydrogen Bond and CEI to Enhanced Lithium-Ion Battery Performance

• Published in: ACS applied materials & interfaces 2024-11, Vol.16 (44), p.61293-61304
• Main Authors: Lin, Zhiyuan, Zhang, Li, Lin, Chenxiao, Yu, Ruoxin, Guo, Guanghua, Chen, Fang, Chen, Weihan, Li, Yunhang, Xia, Yonggao
• Format: Article
• Language: English
• Subjects: cathodes; electrolytes; hydrogen; hydrogen bonding; interphase; lithium batteries; solvents; Surfaces, Interfaces, and Applications
• ISSN: 1944-8244; 1944-8252; 1944-8252
• DOI: 10.1021/acsami.4c13009

The stability of the commercial electrolyte is linked to the internal solvent molecule, particularly in enhancing the stability of these molecules. Hereby, we introduce a dual function strategy involving hydrogen bond induced solvent molecules and the in situ fabrication cathode–electrolyte interphase (CEI) to address this issue. The additive N-(4-(2,5-dioxo-4-oxazolidinyl)­butyl)-2,2,2-trifluoro­acetamide (DOTFA), with its oxazolidinyl and trifluoro­acetamide functional units, establishes hydrogen bonds with the solvent, forming CEI films on the cathode surface that enhance the antioxidation ability of the electrolyte. These hydrogen bonds contribute to enhancing the high-pressure structural stability of the solvent molecule. Additionally, the uniform and robust in situ constructed CEI films act as a shield, protecting the cathode from various side reactions and enhancing interface compatibility. By incorporation of the DOTFA additive in the electrolyte, lithium-ion batteries with NCM811 cathodes exhibit excellent cycling performance. The work highlights the significance of dual function in solvent molecules and provides an effective method for enhancing the antioxidation ability of the electrolyte.