A novel iron molybdate photocatalyst with heterojunction-like band gap structure for organic pollutant degradation by activation of persulfate under simulated sunlight irradiation

• Published in: Environmental science and pollution research international 2023-04, Vol.30 (18), p.53157-53176
• Main Authors: Zhang, Xinyi, Liu, Weibao, Gao, Tianyue, Cao, Dongran, Che, Xinrong, Zhou, Shengwen, Shang, Jiangwei, Cheng, Xiuwen
• Format: Article
• Language: English
• Subjects: Antibiotics; Aquatic Pollution; Atmospheric Protection/Air Quality Control/Air Pollution; Carbamazepine; Catalysts; Contaminants; Degradation; Dyes; Earth and Environmental Science; Ecotoxicology; Electron paramagnetic resonance; electron paramagnetic resonance spectroscopy; Electron spin resonance; Environment; Environmental Chemistry; Environmental Health; Environmental Pollutants; Environmental science; Heterojunctions; Iron; Irradiation; lighting; Malachite green; methyl orange; Methylene blue; Molybdate; molybdates; Nanoparticles; Norfloxacin; Optoelectronics; Organic contaminants; Organic wastes; Oxidation; Oxidation-Reduction; Performance degradation; photocatalysts; Pollutants; pollution; Radiation; Research Article; Rhodamine; rhodamines; semiconductors; species; Sulfamethoxazole; Sunlight; Tartrazine; tetracycline; Waste Water Technology; wastewater; Wastewater treatment; Water Management; Water Pollutants, Chemical - analysis; Water Pollution Control; Water treatment
• ISSN: 1614-7499; 0944-1344; 1614-7499
• DOI: 10.1007/s11356-023-26056-8

Advanced oxidation processes (AOPs) applied to wastewater treatment have become increasingly well developed and the ability of a single technology to remove difficult organic pollutants is limited. One of the main limiting factors is the insufficient variety and quantity of active species generated during the reaction process and catalyst failure. The coupling of the two methods is a practical and effective approach. In this study, different types of semiconductor persulfate (PS) activators, iron molybdate nanoparticles (I-FeMoO 4 , II-FeMoO 4 , and III-FeMoO 4 ), were synthesized by simple solvothermal and calcination methods and applied to photo-assisted activation of PS systems. In addition, the relationship between the intrinsic physicochemical and optoelectronic properties of FeMoO 4 and the catalytic degradation performance was revealed by a series of characterization tools, and the dominant catalysts were screened. At an unadjusted pH of 4.86, 0.6 g L −1 of PS and 0.4 g L −1 of I-FeMoO 4 could achieve efficient degradation of several difficult organic dye contaminants (rhodamine b (Rh B), methylene blue (MB), malachite green (MG), methyl orange (MO), and tartrazine (TTZ)) and other antibiotic contaminants (sulfamethoxazole (SMX), tetracycline (TC), norfloxacin (NOR), and carbamazepine (CBZ)) within 5–60 min. Possible degradation mechanisms in the I-FeMoO 4 /PS/Light reaction system were suggested by radical trapping experiments and electron paramagnetic resonance (EPR) tests. Recovery tests demonstrated that I-FeMoO 4 has good recoverable stability and did not cause secondary pollution. Finally, our study provided a new perspective on the application of coupled wastewater treatment technologies in the practical treatment of organic wastewater.