Synthesis of β,β-Dithioketones by Merging C–C and C–S Bond Cleavage in [1 + 1 + 1 + 1 + 1 + 1] Annulation

An unconventional [1 + 1 + 1 + 1 + 1 + 1] annulation process was developed for the construction of β,β-dithioketones by merging C–C and C–S bond cleavage. In this reaction, rongalite concurrently served as triple C1 units, dual sulfur­(II) synthons, and a reductant for the first time. Mechanism inve...

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Bibliographic Details
Published in:Organic letters 2024-05, Vol.26 (20), p.4340-4345
Main Authors: Yang, Dong-Sheng, Chen, Xiang-Long, Wu, Chun-Yan, Tang, Bo-Cheng, Xiao, Yong-Cheng, Wu, Yan-Dong, Wu, An-Xin
Format: Article
Language:English
Subjects:
cleavage (chemistry)
methodology
reducing agents
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