Heat-moisture treatment to modify structure and functionality and reduce digestibility of wrinkled and round pea starches

Heat-moisture treatment (HMT) was employed to modify wrinkled pea (74.2 % and 76.5 % amylose) and round pea starches (35.9 % and 34.8 % amylose) at 35.0 % moisture, 110 or 130 °C, and 6 h. HMT increased the gelatinization temperatures and decreased the gelatinization enthalpy changes, reduced the pa...

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Bibliographic Details
Published in:Carbohydrate polymers 2024-01, Vol.324, p.121506-121506, Article 121506
Main Authors: Cheng, Fan, Ren, Yikai, Warkentin, Thomas D, Ai, Yongfeng
Format: Article
Language:English
Subjects:
amylose
Amylose - chemistry
calorimetry
crystal structure
digestibility
enthalpy
gelatinization
gels
hardness
Hot Temperature
peas
Pisum sativum - chemistry
resistant starch
Starch - chemistry
Temperature
thermal stability
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Summary:Heat-moisture treatment (HMT) was employed to modify wrinkled pea (74.2 % and 76.5 % amylose) and round pea starches (35.9 % and 34.8 % amylose) at 35.0 % moisture, 110 or 130 °C, and 6 h. HMT increased the gelatinization temperatures and decreased the gelatinization enthalpy changes, reduced the pasting viscosities and gel hardness, and enhanced the enzymatic resistance of the pea starches in comparison with the native counterparts, with greater extents of changes observed for HMT at 130 °C overall. Although HMT decreased the relative crystallinity and elevated the proportion of amorphous conformation, the remaining double-helical crystallites in the modified samples showed improved thermal stability as revealed by differential scanning calorimetry (DSC). More importantly, the HMT-modified pea starches required a higher heating temperature of 120 °C, rather than 95 °C, in Rapid Visco Analyser to provide greater pasting viscosities and develop firmer gels, suggesting that the modified samples had stronger molecular entanglement than the native counterparts. Such molecular entanglement could also reduce enzymatic digestion of HMT-modified starches after boiling in water. With more diverse functional profiles and increased resistant starch (RS) contents (particularly for the HMT-modified wrinkled pea starches having 22.7-29.9 % RS), the HMT-modified pea starches could be promising new ingredients for food applications.
ISSN:0144-8617
1879-1344
DOI:10.1016/j.carbpol.2023.121506