Tailoring the Synthesis and Stability of Germylenes via Electron-Rich P ═C–P and P ═C–P(=S) Derivatives

The formation of stable germylene species through the attachment of a >Ge(II) center to electron-rich P═C-P and P═C-P(=S) backbones is supported by both experimental and theoretical means. The reaction between the phosphavinylphosphorane Mes*P═C(Cl)-P( -Pr) ( ) and GeCl ·dioxane affords the novel...

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Published in:	Inorganic chemistry 2025-11
Main Authors:	Aghion, Iulia-Andreea, Septelean, Raluca, Moraru, Ionut-Tudor, Cristea, Adrian, Soran, Albert, Nemes, Gabriela
Format:	Article
Language:	English
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