Solvents in salt electrolyte: Benefits and possible use as electrolyte for lithium-ion battery

• Published in: Electrochimica acta 2008-07, Vol.53 (17), p.5496-5502
• Main Authors: Taggougui, M., Diaw, M., Carré, B., Willmann, P., Lemordant, D.
• Format: Article
• Language: English
• Subjects: Applied sciences; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Electrochemical window; Electrolyte; Exact sciences and technology; Ionic conductivity; Ionic liquid; Lithium-ion batteries; Viscosity; VTF theory
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2008.03.012

An EC/DEC [40:60% (v/v)] solvent mixture has been added in various amounts to the ionic liquid (IL) hexyltrimethylammonium bis(trifluoromethylsulfonyl)imide (N 1116-NTf 2) in the presence of LiNTf 2 (lithium bis(trifluoromethylsulfonyl)imide) as lithium salt for possible use as electrolytes in lithium-ion batteries. These electrolytes exhibit a larger thermal stability than the reference electrolyte EC/DEC [40:60] + LiNTf 2 1 M when the percentage of the IL exceeds 30% (v/v). All studied electrolytes are glass forming ones with an ideal glass transition temperature of ca. −85 °C(±5 °C), which has been determined by application of the VTF theory to conductivity and viscosity measurements and confirmed by DSC ( T g = −90 ± 5 °C). An electrochemical window of about 5 V versus Li/Li + was measured at a glassy carbon electrode. The cycling ability of the optimized electrolyte N 1116-NTf 2/EC:DEC (40/60% (v/v)) + 1 M LiNTf 2 has been investigated at a titanate oxide (Li 4Ti 5O 12) and a cobalt oxide (Li x CoO 2) electrodes. Cycling the positive and the negative electrodes was conducted successfully with a high capacity and without any significant fading.