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Zinc-proline catalyzed pathway for the formation of sugars
Zn-proline catalyzes the aldolisation of unprotected glycolaldehyde in water to give tetroses and hexoses; threose (33% of the product mixture) was formed with 10% enantiomeric excess of the D-isomer.
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Published in: | Chemical communications (Cambridge, England) England), 2004-07 (13), p.1540-1541 |
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container_end_page | 1541 |
container_issue | 13 |
container_start_page | 1540 |
container_title | Chemical communications (Cambridge, England) |
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creator | Kofoed, Jacob Machuqueiro, Miguel Reymond, Jean-Louis Darbre, Tamis |
description | Zn-proline catalyzes the aldolisation of unprotected glycolaldehyde in water to give tetroses and hexoses; threose (33% of the product mixture) was formed with 10% enantiomeric excess of the D-isomer. |
doi_str_mv | 10.1039/b404465g |
format | article |
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source | Royal Society of Chemistry: Jisc Collections: Journals Archive 1841-2007 (2019-2023) |
subjects | Acetaldehyde - analogs & derivatives Acetaldehyde - chemistry Carbohydrates - chemical synthesis Catalysis Hexoses - chemical synthesis Molecular Structure Proline - chemistry Solutions Stereoisomerism Tetroses - chemical synthesis Zinc - chemistry |
title | Zinc-proline catalyzed pathway for the formation of sugars |
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